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Maroon 5 frontman Adam Levine, 33, was there with fellow band mate, James Valentineto, to accept the award for Favorite Band .
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Fergie's other half and star of the upcoming movie 'Safe Haven' with Julianne Hough, Josh Duhamel, 40, looked H-O-T in a simple navy suit.
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'Safe Haven' star, Julianne Hough, 24, worked the red carpet in a crystal embellished dress and presented the award for Favorite Comedic Movie Actress.
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Matt Bomer, 35, looked dapper in blue on the red carpet. He later presented an award with Chloe Grace Mortez.
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"She's all that" and more in a sexy, strapless teal number. Rachael Leigh Cook, 33, rocked a sweetheart gown and made her comeback to the red carpet in a big way!
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Looking chic in royal blue, Sandra Bullock, 48, was the first ever recipient of the People Choice’s Favorite Humanitarian Award!