50 Shades of Blue

Maroon 5 frontman Adam Levine, 33, was there with fellow band mate, James Valentineto, to accept the award for Favorite Band .

Fergie's other half and star of the upcoming movie 'Safe Haven' with Julianne Hough, Josh Duhamel, 40, looked H-O-T in a simple navy suit.

'Safe Haven' star, Julianne Hough, 24, worked the red carpet in a crystal embellished dress and presented the award for Favorite Comedic Movie Actress.

Matt Bomer, 35, looked dapper in blue on the red carpet. He later presented an award with Chloe Grace Mortez.

"She's all that" and more in a sexy, strapless teal number. Rachael Leigh Cook, 33, rocked a sweetheart gown and made her comeback to the red carpet in a big way!

Looking chic in royal blue, Sandra Bullock, 48, was the first ever recipient of the People Choice’s Favorite Humanitarian Award!